There are a number of 3rd party solutions to move Contacts from Outlook to a Galaxy phone. What you need to decide is whether to move everything via Google, or whether to go direct. If you go through Google, you are limited to Contacts and Calendar only. Other solutions can bring in Tasks, Notes and Journal sync.
CompanionLink ($14.95) can handle moving stuff to Google, or alternately doing it directly with USB or through CompanionLink's Cloud server.