My Verizon from the Android device can only be accessed using our network because it is set up using a portal directly on our network.
If you want to access your My Verizon account from your Android device using a WiFi connection you will need to open a browser page on your phone and then go to www.verizonwireless.com. Once there you can sign in to your My Verizon account.
Hope this helps. Feel free to contact us if you have any further questions.